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Subpart T—Secondary Molybdenum and Vanadium Subcategory

Source:

50 FR 38357, Sept. 20, 1985, unless otherwise noted.

§ 421.220 Applicability: Description of the secondary molybdenum and vanadium subcategory.

The provisions of this subpart are applicable to discharges resulting from the production of molybdenum or vanadium by secondary molybdenum and vanadium facilities.

§ 421.221 Specialized definitions.

For the purpose of this subpart the general definitions, abbreviations, and methods of analysis set forth in 40 CFR part 401 shall apply to this subpart.

§ 421.222 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable technology currently available:

(a) Leach tailings.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 40.778 18.145
Chromium 8.585 3.512
Lead 8.195 3.902
Nickel 37.460 24.779
Iron 23.410 11.902
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 8078.000 3551.000
Total Suspended Solids 799.950 380.460
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(b) Molybdenum filtrate solvent extraction raffinate.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 121.720 54.162
Chromium 25.625 10.483
Lead 24.460 11.648
Nickel 111.819 73.964
Iron 69.887 35.526
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 24114.000 10600.000
Total Suspended Solids 2387.800 1135.660
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(c) Vanadium decomposition wet air pollution control.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of vanadium produced by decomposition
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000
Total suspended solids 0.000 0.000
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(d) Molybdenum drying wet air pollution control.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000
Total suspended solids 0.000 0.000
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(e) Pure Grade Molybdenum.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic 48.655 21.650
Chromium 10.243 4.190
Lead 9.778 4.656
Nickel 44.698 29.566
Iron 27.936 14.201
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 9638.000 4237.000
Total Suspended Solids 954.480 453.960
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31703, Aug. 3, 1990]

§ 421.223 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:

(a) Leach Tailings.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 27.120 12.097
Chromium 7.219 2.927
Lead 5.463 2.536
Nickel 10.731 7.219
Iron 23.413 11.902
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 8078.000 3551.000

(b) Molybdenum filtrate solvent extraction raffinate.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 80.952 36.108
Chronium 21.548 8.736
Lead 16.306 7.571
Nickel 32.031 21.548
Iron 69.887 35.526
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 24114.000 10600.000

(c) Vanadium decomposition wet air pollution control.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of vanadium produced by decomposition
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000

(d) Molybdenum drying wet air pollution control.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000

(e) Pure Grade Molybdenum.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic 32.359 14.434
Chromium 8.614 3.492
Lead 6.518 3.026
Nickel 12.804 8.614
Iron 27.936 14.201
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 9638.000 4237.000

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31703, 31704, Aug. 3, 1990]

§ 421.224 Standards of performance for new sources.

Any new source subject to this subpart shall achieve the following new source performance standards:

(a) Leach tailings.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 27.120 12.097
Chromium 7.219 2.927
Lead 5.463 2.536
Nickel 10.731 7.219
Iron 23.413 11.902
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 8078.000 3551.000
Total Suspended Solids 292.665 234.132
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(b) Molybdenum filtrate solvent extraction raffinate.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 80.952 36.108
Chromium 21.548 8.736
Lead 16.306 7.571
Nickel 32.031 21.548
Iron 69.887 35.526
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 24114.000 10600.000
Total Suspended Solids 873.585 698.868
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(c) Vanadium decomposition wet air pollution control.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum and vanadium produced
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000
Total suspended solids 0.000 0.000
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(d) Molybdenum drying wet air pollution control.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum and vanadium produced
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000
Total suspended solids 0.000 0.000
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(e) Pure Grade Molybdenum.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic 32.359 14.434
Chromium 8.614 3.492
Lead 6.518 3.026
Nickel 12.804 8.614
Iron 27.936 14.201
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 9638.000 4237.000
Total Suspended Solids 349.200 279.360
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31704, Aug. 3, 1990]

§ 421.225 [Reserved]

§ 421.226 Pretreatment standards for new sources.

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants in secondary molybdenum and vanadium process wastewater introduced into a POTW shall not exceed the following values:

(a) Leach tailings.

PSNS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 27.120 12.097
Chromium 7.219 2.927
Lead 5.463 2.536
Nickel 10.731 7.219
Iron 23.413 11.902
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 8078.000 3551.000

(b) Molybdenum filtrate solvent extraction raffinate.

PSNS for the Secondary Molybdenum And Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic 80.952 36.108
Chromium 21.548 8.736
Lead 16.306 7.571
Nickel 32.031 21.548
Iron 69.887 35.526
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 24114.000 10600.000

(c) Vanadium decomposition wet air pollution control.

PSNS for the Secondary Molybdenum and Vandadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) vanadium produced by decomposition
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000

(d) Molybdenum drying wet air pollution control.

PSNS for the Secondary Molybdenum and Vandadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic 0.000 0.000
Chromium 0.000 0.000
Lead 0.000 0.000
Nickel 0.000 0.000
Iron 0.000 0.000
Molybdenum 0.000 0.000
Ammonia (as N) 0.000 0.000

(e) Pure Grade Molybdenum.

PSNS for the Secondary Molybdenum And Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic 32.359 14.434
Chromium 8.614 3.492
Lead 6.518 3.026
Nickel 12.804 8.614
Iron 27.936 14.201
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 9638.000 4237.000

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31704, 31705 Aug. 3, 1990]

§ 421.227 [Reserved]