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Subpart S—Primary Molybdenum and Rhenium Subcategory

Source:

50 FR 38355, Sept. 20, 1985, unless otherwise noted.

§ 421.210 Applicability: Description of the primary molybdenum and rhenium subcategory.

The provisions of this subpart are applicable to discharges resulting from the production of molybdenum and rhenium facilities.

§ 421.211 Specialized definitions.

For the purpose of this subpart the general definitions, abbreviations, and methods of analysis set forth in 40 CFR part 401 shall apply to this subpart.

§ 421.212 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitation representing the degree of effluent reduction attainable by the application of the best practicable technology currently available:

(a) Molybdenum sulfide leachate.

BPT Limitations for the Primary Molybdenum Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide leached
Arsenic 0.968 0.431
Lead 0.195 0.093
Nickle 0.889 0.588
Selenium 0.570 0.255
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 61.720 27.130
Fluoride 16.210 9.214
Total suspended solids 18.980 9.029
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(b) Roaster SO2 scrubber.

BPT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant of pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 3.509 1.561
Lead 0.705 0.336
Nickel 3.224 2.133
Selenium 2.065 0.924
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 223.800 98.390
Fluoride 58.770 33.410
Total suspended solids 68.840 32.740
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(c) Molybdic oxide leachate.

BPT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum contained in molybdic oxide leached
Arsenic 24.210 10.770
Lead 4.865 2.317
Nickel 22.240 14.710
Selenium 14.250 6.371
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 1,544.000 678.800
Fluoride 405.400 230.500
Total suspended solids 474.900 225.900
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(d) Hydrogen reduction furnace scrubber.

BPT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum metal powder produced
Arsenic 47.860 21.300
Lead 9.617 4.580
Nickel 43.970 29.080
Selenium 28.170 12.600
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 3,052.000 1,342.000
Fluoride 801.400 455.700
Total suspended solids 938.800 446.500
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(e) Depleted rhenium scrubbing solution.

BPT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 1.497 0.666
Lead 0.301 0.143
Nickel 1.375 0.909
Selenium 0.881 0.394
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 95.440 41.960
Fluoride 25.060 14.250
Total suspended solids 29.360 13.960
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38355, Sept. 20, 1985, as amended at 55 FR 31701, Aug. 3, 1990]

§ 421.213 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:

(a) Molybdenum sulfide leachate.

BAT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds million pounds) of molybdenum sulfide leached
Arsenic 0.644 0.287
Lead 0.130 0.060
Nickel 0.255 0.171
Selenium 0.380 0.171
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 61.720 27.130
Fluoride 16.210 9.214

(b) Roaster SO2 scrubber.

BAT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per/million pounds) of molybdenum sulfide roasted
Arsenic 2.334 1.041
Lead 0.470 0.218
Nickel 0.924 0.621
Selenium 1.377 0.621
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 223.800 98.390
Fluoride 58.770 33.410

(c) Molybdic oxide leachate.

BAT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per/million pounds) of molybdenum contained in molybdic oxide leached
Arsenic 16.100 7.182
Lead 3.244 1.506
Nickel 6.371 4.286
Selenium 9.499 4.286
Molybdenum [Reserved] [Reserved]
Ammonia (as N) 1,544.000 678.800
Fluoride 405.400 230.500

(d) Hydrogen reduction furnace scrubber.

BAT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per/million pounds) of molybdenum metal powder produced
Arsenic 3.183 1.420
Lead 0.641 0.298
Nickel 1.260 0.847
Selenium 1.878 0.847
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 305.300 134.200
Fluoride 80.150 45.570

(e) Depleted rhenium scrubbing solution.

BAT Limitations for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per/million pounds) of molybdenum sulfide roasted
Arsenic 0.995 0.444
Lead 0.201 0.093
Nickel 0.394 0.265
Selenium 0.587 0.265
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 95.440 41.960
Fluoride 25.060 14.250

[50 FR 38355, Sept. 20, 1985, as amended at 55 FR 31701, 31702, Aug. 3, 1990]

§ 421.214 Standards of performance for new sources.

Any new source subject to this subpart shall achieve the following new source performance standards:

(a) Molybdenum sulfide leachate.

NSPS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide leached
Arsenic 0.644 0.287
Lead 0.130 0.060
Nickel 0.255 0.171
Selenium 0.380 0.171
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 61.720 27.130
Fluoride 16.210 9.214
Total suspended solids 6.945 5.556
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(b) Roaster SO2 scrubber.

NSPS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 2.334 1.041
Lead 0.470 0.218
Nickel 0.924 0.621
Selenium 1.377 0.621
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 223.800 98.390
Fluoride 58.770 33.410
Total suspended solids 25.190 20.150
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(c) Molybdic oxide leachate.

NSPS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum contained in molybdic oxide leached
Arsenic 16.100 7.182
Lead 3.244 1.506
Nickel 6.371 4.286
Selenium 9.499 4.286
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 1,544.000 678.800
Fluoride 405.400 230.500
Total suspended solids 173.800 139.000
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(d) Hydrogen reduction furnace scrubber.

NSPS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum metal powder produced
Arsenic 3.183 1.420
Lead 0.641 0.298
Nickel 1.260 0.847
Selenium 1.878 0.847
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 305.300 134.200
Fluoride 80.150 45.570
Total suspended solids 34.350 27.480
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

(e) Depleted rhenium scrubbing solution.

NSPS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 0.995 0.444
Lead 0.201 0.093
Nickel 0.394 0.265
Selenium 0.587 0.265
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 95.440 41.960
Fluoride 25.060 14.250
Total suspended solids 10.740 8.592
pH (1) (1)
1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38355, Sept. 20, 1985, as amended at 55 FR 31702, Aug. 3, 1990]

§ 421.215 [Reserved]

§ 421.216 Pretreatment standards for new sources.

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants in primary molybdenum and rhenium process wastewater introduced into a POTW shall not exceed the following values:

(a) Molybdenum sulfide leachate.

PSNS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide leached
Arsenic 0.644 0.287
Lead 0.130 0.060
Nickel 0.255 0.171
Selenium 0.380 0.171
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 61.720 27.130
Fluoride 16.210 9.214

(b) Roaster SO2 scrubber.

PSNS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 2.334 1.041
Lead 0.470 0.218
Nickel 0.924 0.621
Selenium 1.377 0.621
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 223.800 98.390
Fluoride 58.770 33.410

(c) Molybdic oxide leachate.

PSNS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum contained in molybdic oxide leached
Arsenic 16.100 7.182
Lead 3.244 1.506
Nickel 6.371 4.286
Selenium 9.499 4.286
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 1,544.000 678.800
Fluoride 405.400 230.500

(d) Hydrogen reduction furnace scrubber.

PSNS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum metal powder produced
Arsenic 3.183 1.420
Lead 0.641 0.298
Nickel 1.260 0.847
Selenium 1.878 0.847
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 305.300 134.200
Fluoride 80.150 45.570

(e) Depleted rhenium scrubbing solution.

PSNS for the Primary Molybdenum and Rhenium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum sulfide roasted
Arsenic 0.995 0.444
Lead 0.201 0.093
Nickel 0.394 0.265
Selenium 0.587 0.265
Molybdenum [Reserved] [Reserved].
Ammonia (as N) 95.440 41.960
Fluoride 25.060 14.250

[50 FR 38355, Sept. 20, 1985, as amended at 55 FR 31702, 31703, Aug. 3, 1990]

§ 421.217 [Reserved]