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Electronic Code of Federal Regulations

e-CFR data is current as of December 12, 2019

Title 40Chapter ISubchapter CPart 63Subpart UUU → Appendix


Title 40: Protection of Environment
PART 63—NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED)
Subpart UUU—National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units


Table 34 to Subpart UUU of Part 63—Continuous Compliance With HAP Emission Limits for Sulfur Recovery Units

As stated in §63.1568(c)(1), you shall meet each requirement in the following table that applies to you.

For .  .  .For this emission limit .  .  .You shall demonstrate continuous compliance by .  .  .
1. Subject to NSPS. Each new or existing Claus sulfur recovery unit part of a sulfur recovery plant with design capacity greater than 20 LTD and subject to the NSPS for sulfur oxides in 40 CFR 60.104(a)(2) or 60.102a(f)(1)a. 250 ppmv (dry basis) of SO2 at zero percent excess air, or concentration determined using Equation 1 of 40 CFR 60.102a(f)(1)(i), if you use an oxidation or reduction control system followed by incinerationCollecting the hourly average SO2 monitoring data (dry basis, percent excess air) and, if using Equation 1 of 40 CFR 60.102a(f)(1)(i), collecting the hourly O2 concentration or flow monitoring data according to §63.1572; determining and recording each 12-hour rolling average concentration of SO2; maintaining each 12-hour rolling average concentration of SO2 at or below the applicable emission limitation; and reporting any 12-hour rolling average concentration of SO2 greater than the applicable emission limitation in the semiannual compliance report required by §63.1575.
   b. 300 ppmv of reduced sulfur compounds calculated as ppmv SO2 (dry basis) at zero percent excess air, or concentration determined using Equation 1 of 40 CFR 60.102a(f)(1)(i), if you use a reduction control system without incinerationCollecting the hourly average reduced sulfur (and air or O2 dilution and oxidation) monitoring data and, if using Equation 1 of 40 CFR 60.102a(f)(1)(i), collecting the hourly O2 concentration or flow monitoring data according to §63.1572; determining and recording each 12-hour rolling average concentration of reduced sulfur; maintaining each 12-hour rolling average concentration of reduced sulfur at or below the applicable emission limitation; and reporting any 12-hour rolling average concentration of reduced sulfur greater than the applicable emission limitation in the semiannual compliance report required by §63.1575.
2. Option 1: Elect NSPS. Each new or existing sulfur recovery unit (Claus or other type, regardless of size) not subject to the NSPS for sulfur oxides in 40 CFR 60.104(a)(2) or 60.102a(f)(1)a. 250 ppmv (dry basis) of SO2 at zero percent excess air, or concentration determined using Equation 1 of 40 CFR 60.102a(f)(1)(i), if you use an oxidation or reduction control system followed by incinerationCollecting the hourly average SO2 data (dry basis, percent excess air) and, if using Equation 1 of 40 CFR 60.102a(f)(1)(i), collecting the hourly O2 concentration or flow monitoring data according to §63.1572; determining and recording each 12-hour rolling average concentration of SO2; maintaining each 12-hour rolling average concentration of SO2 at or below the applicable emission limitation; and reporting any 12-hour rolling average concentration of SO2 greater than the applicable emission limitation in the semiannual compliance report required by §63.1575.
   b. 300 ppmv of reduced sulfur compounds calculated as ppmv SO2 (dry basis) at zero percent excess air, or concentration determined using Equation 1 of 40 CFR 60.102a(f)(1)(i), if you use a reduction control system without incinerationCollecting the hourly average reduced sulfur (and air or O2 dilution and oxidation) monitoring data and, if using Equation 1 of 40 CFR 60.102a(f)(1)(i), collecting the hourly O2 concentration or flow monitoring data according to §63.1572; determining and recording each 12-hour rolling average concentration of reduced sulfur; maintaining each 12-hour rolling average concentration of reduced sulfur at or below the applicable emission limitation; and reporting any 12-hour rolling average concentration of reduced sulfur greater than the applicable emission limitation in the semiannual compliance report required by §63.1575.
3. Option 2: TRS limit. Each new or existing sulfur recovery unit (Claus or other type, regardless of size) not subject to the NSPS for sulfur oxides in 40 CFR 60.104(a)(2) or 60.102a(f)(1)300 ppmv of TRS compounds, expressed as an SO2 concentration (dry basis) at zero percent oxygen or reduced sulfur compounds calculated as ppmv SO2 (dry basis) at zero percent excess airi. If you use continuous parameter monitoring systems, collecting the hourly average TRS monitoring data according to §63.1572 and maintaining each 12-hour average concentration of TRS at or below the applicable emission limitation; or
   ii. If you use a continuous emission monitoring system, collecting the hourly average TRS monitoring data according to §63.1572, determining and recording each 12-hour rolling average concentration of TRS; maintaining each 12-hour rolling average concentration of TRS at or below the applicable emission limitation; and reporting any 12-hour rolling average TRS concentration greater than the applicable emission limitation in the semiannual compliance report required by §63.1575.

[80 FR 75315, Dec. 1, 2015]

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